High electronic couplings of single mesitylene molecular junctions

• Yuki Komoto,
• Shintaro Fujii,
• Tomoaki Nishino and
• Manabu Kiguchi

Beilstein J. Nanotechnol. 2015, 6, 2431–2437, doi:10.3762/bjnano.6.251

• electrode perpendicular to the charge transport direction and (ii) mesitylene has tilted from the perpendicular orientation. Keywords: break junction; charge transport; mesitylene; single molecular junction; scanning tunnelling microscopy (STM); Introduction Along with increasing interests in molecular

• electronics on the single molecular scale [1], much efforts have been devoted to understand charge transport in a single molecular junction, in which a single molecule is wired to two metal electrodes. In recent years single molecular junctions with electronic functionalities such as diodes [2][3][4][5][6][7

• , electronic conductance of the single molecular junction can be described by two parameters of (i) the electronic coupling between electrodes and molecule and (ii) the relative energy level alignment of the conduction orbital of molecule with respect to the Fermi level of the metal electrodes. By fitting the

An MCBJ case study: The influence of π-conjugation on the single-molecule conductance at a solid/liquid interface

• Wenjing Hong,
• Hennie Valkenier,
• Gábor Mészáros,
• David Zsolt Manrique,
• Artem Mishchenko,
• Alexander Putz,
• Pavel Moreno García,
• Colin J. Lambert,
• Jan C. Hummelen and
• Thomas Wandlowski

Beilstein J. Nanotechnol. 2011, 2, 699–713, doi:10.3762/bjnano.2.76

• is equal to 2.5 nS, the most probable single-molecular junction conductance of AC from a limited data set of three individual traces. (Note that the complete, statistically significant analysis is reported below in the section "Comparative conductance measurements of AC with AQ and AH"). Applying the

• was obtained from the statistical analysis of 2000 individual traces acquired with our STM-BJ setup [15][16][33]. Both the red and the black graphs display clear peaks at 1 G0 and 10−4.4–10−4.5 G0, which are assigned to the breaking of a monatomic gold–gold contact and the single molecular junction